| Section |
Topics Covered |
Key Terms |
| 2.1 Chemical Properties |
Acids/bases in lab, reactions with metals, metal carbonates, hydrogencarbonates, neutralisation, metallic & non-metallic oxides |
Indicator, Olfactory indicator, Neutralisation, Salt, Basic oxide, Acidic oxide |
| 2.2 Common Properties |
HβΊ ions in acids, OHβ» ions in bases, ionisation in water, dilution, exothermic dissolution, strong vs weak acids/bases |
HβΊ(aq), Hydronium ion HβOβΊ, OHβ»(aq), Alkali, Dilution, Ionisation |
| 2.3 pH Scale |
Universal indicator, pH 0–14, importance of pH in everyday life, acid rain, tooth decay, digestive system |
pH, Universal indicator, Acid rain, Antacid, Strong acid, Weak acid |
| 2.4 More About Salts |
Family of salts, pH of salts, chlor-alkali process, bleaching powder, baking soda, washing soda, water of crystallisation, Plaster of Paris |
Brine, Chlor-alkali, NaHCOβ, NaβCOβ, Water of crystallisation, Gypsum, Plaster of Paris |
Acid: A substance that produces hydrogen ions (HβΊ) or hydronium ions (HβOβΊ) when dissolved in water. Acids are sour in taste, turn blue litmus red, and have pH less than 7. Examples: HCl, HβSOβ, HNOβ, CHβCOOH.
Base: A substance that produces hydroxide ions (OHβ») when dissolved in water. Bases are bitter in taste, soapy to touch, turn red litmus blue, and have pH more than 7. Examples: NaOH, Ca(OH)β, KOH, Mg(OH)β.
Alkali: A base that is soluble in water. All alkalis are bases, but not all bases are alkalis. Alkalis are soapy to touch, bitter and corrosive. Examples: NaOH, KOH, Ca(OH)β dissolved in water.
Indicator: A substance that shows different colours in acidic and basic solutions, used to detect whether a substance is an acid or a base. Examples: litmus (natural), phenolphthalein and methyl orange (synthetic).
Olfactory Indicator: A substance whose odour changes in acidic or basic medium. Examples: onion (loses smell in base), vanilla (loses smell in base), clove oil (loses smell in acid).
Neutralisation Reaction: The reaction between an acid and a base to form a salt and water. The acid and base neutralise each other’s effects. General form: Acid + Base → Salt + Water. At the ionic level: HβΊ(aq) + OHβ»(aq) → HβO(l).
Salt: An ionic compound formed when the hydrogen of an acid is replaced by a metal (or ammonium). Salts are formed in neutralisation reactions between acids and bases. Example: NaCl (common salt) from HCl + NaOH.
pH Scale: A scale (0 to 14) that measures the concentration of hydrogen ions in a solution. pH 7 = neutral; pH < 7 = acidic; pH > 7 = basic/alkaline. The ‘p’ in pH stands for ‘potenz’ (German for power). Higher HβΊ concentration = lower pH.
Strong Acid: An acid that completely ionises in water to produce a large number of HβΊ ions. Examples: HCl, HβSOβ, HNOβ. A weak acid only partially ionises — e.g., CHβCOOH (acetic acid).
Water of Crystallisation: The fixed number of water molecules present in one formula unit of a crystalline salt. Example: CuSOβ·5HβO has 5 water molecules. When heated, these water molecules are lost and the colour changes (blue CuSOβ turns white).
Plaster of Paris: Calcium sulphate hemihydrate (CaSOβ·½HβO), obtained by heating gypsum (CaSOβ·2HβO) at 373K. On mixing with water, it sets into a hard solid (gypsum). Used for fractured bones, toys, smooth surfaces.
Chlor-alkali Process: The electrolysis of brine (aqueous NaCl) which produces three useful products: chlorine gas (at anode), hydrogen gas (at cathode), and sodium hydroxide solution (near cathode). Reaction: 2NaCl(aq) + 2HβO(l) → 2NaOH(aq) + Clβ(g) + Hβ(g).
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2.1 — Chemical Properties of Acids and Bases |
Acids and bases have been known since ancient times — acids for their sour taste and bases for their bitter taste and soapy feel. However, we never taste chemicals directly in the laboratory. Instead, we use indicators to test them. Litmus (extracted from lichen, a plant in the Thallophyta division) is the most common natural indicator — it turns red in acid and blue in base.
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π Diagram 1: Indicator Colour Chart |
| Indicator |
In Acid |
In Base |
In Neutral |
| Blue Litmus |
Turns RED |
Stays BLUE |
Stays Blue |
| Red Litmus |
Stays RED |
Turns BLUE |
Stays Red |
| Phenolphthalein |
Colourless |
PINK/Red |
Colourless |
| Methyl Orange |
RED/Pink |
YELLOW |
Orange |
| Turmeric |
Yellow |
Reddish-brown |
Yellow |
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2.1.2 — How do Acids and Bases React with Metals? |
When acids react with metals, they displace hydrogen gas and form a salt. When bases (like NaOH) react with certain metals (like zinc, aluminium), they also produce hydrogen gas along with a salt. The hydrogen burns with a ‘pop’ sound — the test for Hβ gas.
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π Diagram 2: Zinc + Dilute Sulphuric Acid (Activity 2.3) |
| Delivery tube |
| ↓ |
| Hβ gas bubbles ↑
Dilute HβSOβ ••••• Zn granules |
|
Reactions:
Acid + Metal → Salt + Hβ gas
Zn + HβSOβ → ZnSOβ + Hβ↑ Zn + 2HCl → ZnClβ + Hβ↑ Mg + 2HCl → MgClβ + Hβ↑
Base + Metal → Salt + Hβ: 2NaOH + Zn → NaβZnOβ + Hβ↑ (Sodium zincate)
Test for Hβ: Burns with a pop sound when candle brought near. |
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2.1.3 — Metal Carbonates and Hydrogencarbonates with Acids |
All metal carbonates and hydrogencarbonates react with acids to produce a salt, carbon dioxide gas and water. The COβ gas produced turns lime water milky — this is the standard test for COβ.
Metal carbonate / Hydrogencarbonate + Acid → Salt + COβ + Water
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π Diagram 3: COβ passed through Lime Water (Activity 2.5) |
Test Tube A NaβCOβ + HCl → COβ gas |
→ |
Lime Water Ca(OH)β(aq) clear initially |
→ |
Turns MILKY WHITE CaCOβ↓ precipitate! |
Equations: NaβCOβ(s) + 2HCl(aq) → 2NaCl(aq) + HβO(l) + COβ(g) NaHCOβ(s) + HCl(aq) → NaCl(aq) + HβO(l) + COβ(g) Ca(OH)β(aq) + COβ(g) → CaCOβ(s)↓ + HβO(l) [White precipitate = test for COβ] Excess COβ: CaCOβ(s) + HβO(l) + COβ(g) → Ca(HCOβ)β(aq) [Soluble — milkiness disappears] |
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2.1.4 — Neutralisation (Acid + Base) |
When an acid and a base react together, they neutralise each other’s effect to form a salt and water. This is called a neutralisation reaction. Phenolphthalein (pink in base, colourless in acid) is used to detect the endpoint.
General Reaction: Acid + Base → Salt + Water HX + MOH → MX + HβO At ionic level: HβΊ(aq) + OHβ»(aq) → HβO(l)
Example: NaOH(aq) + HCl(aq) → NaCl(aq) + HβO(l) |
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Metal Oxide + Acid (similar to neutralisation): Metal oxide + Acid → Salt + Water CuO(s) + 2HCl(aq) → CuClβ(aq) + HβO(l) (Black CuO dissolves → Blue-green CuClβ)
Metallic oxides are basic oxides. Non-metallic oxides (e.g., COβ, SOβ) are acidic oxides. |
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2.2 — What do All Acids and All Bases Have in Common? |
Although glucose and alcohol also contain hydrogen, they are not acids. The key is whether hydrogen ions (HβΊ) are produced in water. Acids dissolve in water to produce HβΊ(aq) ions — these carry electric current, making the bulb glow in Activity 2.8. Glucose and alcohol don’t produce ions, so the bulb does NOT glow with them.
| Substance |
Contains H? |
Produces HβΊ in water? |
Bulb glows? |
Acidic? |
| HCl, HβSOβ, HNOβ |
β Yes |
β Yes |
β Yes |
β Yes |
| Glucose, Alcohol |
β Yes |
β No |
β No |
β No |
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2.2.1 — Acids and Bases in Water: Ionisation |
Dry HCl gas does NOT change the colour of dry litmus paper — proving that HβΊ ions are only produced in the presence of water. HβΊ ions cannot exist alone; they combine with water to form the hydronium ion (HβOβΊ).
Acids in water → HβΊ(aq) or HβOβΊ HCl + HβO → HβOβΊ + Clβ» HβSOβ → 2HβΊ + SOβ²β» HβΊ + HβO → HβOβΊ |
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Bases in water → OHβ»(aq) NaOH → NaβΊ(aq) + OHβ»(aq) KOH → KβΊ(aq) + OHβ»(aq) Mg(OH)β → Mg²βΊ(aq) + 2OHβ»(aq) |
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β Safety Rule: Always add ACID to WATER (A to W), never water to acid. Dissolving acid in water is highly exothermic — adding water to concentrated acid generates so much heat it can cause splashing and burns!
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2.3 — How Strong are Acid or Base Solutions? The pH Scale |
The pH scale (0–14) measures hydrogen ion concentration in a solution. It uses a universal indicator — a mixture of several indicators that shows a different colour for each pH value. The ‘p’ in pH stands for potenz (German: power). Higher HβΊ concentration means lower pH.
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π Diagram 4: The pH Scale (0 to 14) |
0 Very Acidic |
1 Gastric juice |
2 Lemon juice |
3 Vinegar Cola |
4 Tomato juice |
5 Coffee Curd |
6 Urine Milk |
7 NEUTRAL Pure Water |
8 Sea water |
9 Baking soda |
10 Milk of magnesia |
11 Ammonia solution |
12 Lime water |
13 NaOH dil. |
14 Very Alkaline |
| ← ACIDIC (HβΊ concentration increasing) |
N |
(OHβ» concentration increasing) BASIC → |
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2.3.1 — Importance of pH in Everyday Life |
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π« Human Body
Our body works within pH 7.0–7.8. Slightly alkaline blood (pH ~7.4) is essential. Living organisms can survive only in a narrow pH range. Even a slight change in blood pH can be fatal. |
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π¦· Tooth Decay
Tooth decay starts when mouth pH drops below 5.5. Bacteria produce acids from sugar, corroding tooth enamel (calcium hydroxyapatite). Using basic toothpaste neutralises the acid and prevents decay. Clean teeth after meals! |
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π§ Acid Rain
When pH of rain water falls below 5.6, it is called acid rain. It is caused by dissolved SOβ and NOβ from burning of fossil fuels. Acid rain lowers river pH, making aquatic life survival difficult, and damages buildings and soil. |
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π± Soil pH
Plants need a specific pH range for healthy growth. If soil is too acidic, farmers add calcium oxide (quick lime), slaked lime (calcium hydroxide) or chalk (CaCOβ) to neutralise acidity and increase soil pH. |
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π½ Stomach Acid
The stomach produces HCl (pH ~1.2) to digest food. During indigestion, excess acid causes pain. Antacids (mild bases like Mg(OH)β — Milk of magnesia) are used to neutralise excess acid and provide relief. |
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π Animal/Plant Defence
Bee sting injects formic (methanoic) acid — baking soda (base) provides relief. Nettle leaf hairs inject methanoic acid — dock leaf (basic) soothes the pain. Venus atmosphere has HβSOβ clouds — hostile to life! |
| Salt formed from |
Nature of salt |
pH |
Example |
| Strong acid + Strong base |
Neutral |
= 7 |
NaCl (HCl + NaOH) |
| Strong acid + Weak base |
Acidic |
< 7 |
NHβCl (HCl + NHβOH) |
| Weak acid + Strong base |
Basic |
> 7 |
NaβCOβ (HβCOβ + NaOH) |
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2.4.3 — Chemicals from Common Salt (NaCl) |
Common salt (sodium chloride, NaCl) — obtained from sea water or rock salt (mined underground) — is a vital raw material for producing many essential chemicals used in industry and daily life.
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π Diagram 5: The Chlor-alkali Process |
| β‘ ELECTRICITY |
| ↓ passed through brine (NaCl solution) |
At ANODE (+) Clβ gas evolved Uses: PVC, disinfectants, bleaching powder, CFCs |
Near CATHODE NaOH solution Uses: soap, detergents, paper, artificial fibres |
At CATHODE (−) Hβ gas evolved Uses: fuel, margarine, ammonia for fertilisers |
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| Reaction: 2NaCl(aq) + 2HβO(l) → 2NaOH(aq) + Clβ(g) + Hβ(g) |
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π§΄ Sodium Hydroxide (NaOH)
From chlor-alkali process. Formed near cathode. Uses: soaps, detergents, paper making, de-greasing metals, artificial fibres. |
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π Bleaching Powder Ca(ClO)β
Clβ on dry slaked lime: 2Ca(OH)β + 2Clβ → Ca(ClO)β + CaClβ + 2HβO. Uses: bleaching textiles/wood pulp/laundry; oxidising agent; disinfecting drinking water. |
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π₯ Baking Soda NaHCOβ
NaCl + HβO + COβ + NHβ → NHβCl + NaHCOβ. Uses: baking powder (COβ makes bread spongy); antacid; soda-acid fire extinguisher. Mild non-corrosive basic salt. |
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π«§ Washing Soda NaβCOβ·10HβO
Heat NaHCOβ → NaβCOβ; recrystallise with water → NaβCOβ·10HβO. Uses: glass, soap, paper industries; manufacture of borax; cleaning agent; removes permanent water hardness. |
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2.4.4 — Water of Crystallisation & Plaster of Paris |
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π Diagram 6: Copper Sulphate + Water of Crystallisation (Activity 2.15) |
CuSOβ·5HβO BLUE crystals “Hydrated” |
→ HEAT |
CuSOβ WHITE powder “Anhydrous” |
→ + few drops HβO |
CuSOβ·5HβO BLUE restored! |
Water of crystallisation = fixed number of HβO molecules per formula unit. CuSOβ·5HβO has 5; NaβCOβ·10HβO has 10; CaSOβ·2HβO (gypsum) has 2.
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π Diagram 7: Gypsum → Plaster of Paris → Gypsum |
GYPSUM CaSOβ·2HβO White crystalline solid |
→ Heat at 373K (lose 1.5 HβO) |
PLASTER OF PARIS CaSOβ·½HβO White powder |
→ + 1½ HβO (sets hard) |
GYPSUM CaSOβ·2HβO Hard solid mass |
Plaster of Paris must be stored in moisture-proof containers — contact with even a little moisture causes it to set into hard gypsum, making it useless. Uses: fractured bone support, toys, decoration, smooth surfaces. Called “Plaster of Paris” because Paris has large gypsum deposits.
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πΏ Naturally Occurring Acids (Table 2.3) |
| Natural Source |
Acid |
Natural Source |
Acid |
| Vinegar |
Acetic acid (ethanoic acid) |
Sour milk / Curd |
Lactic acid |
| Orange |
Citric acid |
Lemon |
Citric acid |
| Tamarind |
Tartaric acid |
Ant sting |
Methanoic acid (formic acid) |
| Tomato |
Oxalic acid |
Nettle sting |
Methanoic acid (formic acid) |
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π¬ Activities (2.1 to 2.15) — Lab Experiments |
βΆ Activity 2.1 — Testing with Indicators
Materials: HCl, HβSOβ, HNOβ, CHβCOOH, NaOH, Ca(OH)β, KOH, Mg(OH)β, NHβOH; red litmus, blue litmus, phenolphthalein, methyl orange.
Procedure: Put a drop of each solution on a watch-glass. Test with each indicator.
Observations: Acids turn blue litmus red, phenolphthalein stays colourless, methyl orange turns red/pink. Bases turn red litmus blue, phenolphthalein turns pink, methyl orange turns yellow.
Conclusion: Indicators change colour depending on whether the substance is acidic or basic.
βΆ Activity 2.2 — Olfactory Indicators (Onion, Vanilla, Clove)
Materials: Onion-soaked cloth strips, vanilla essence, clove oil, dilute HCl, dilute NaOH.
Procedure: Add HCl and NaOH to onion strips, vanilla and clove oil separately. Note odour changes.
Observations: Onion — loses smell in NaOH (base), retains in HCl. Vanilla — loses smell in base. Clove oil — loses smell in acid (NaOH doesn’t affect it).
Conclusion: Onion and vanilla are olfactory indicators (respond to bases). Clove responds to acids. These can be used to detect acids/bases where colour indicators are not visible.
βΆ Activity 2.3 — Acid + Metal → Hydrogen Gas
Materials: Dilute HβSOβ, zinc granules, soap solution, burning candle. [CAUTION: Teacher’s assistance needed.]
Procedure: Add dilute HβSOβ to Zn granules. Pass evolved gas through soap solution. Bring a burning candle near Hβ-filled bubble.
Observations: Bubbles on Zn surface. Soap bubbles filled with gas rise. The bubble burns with a ‘pop’ sound.
Conclusion: Hβ gas is evolved. Equation: Zn + HβSOβ → ZnSOβ + Hβ↑ [Displacement reaction]. All common acids (HCl, HNOβ, CHβCOOH) give similar results.
βΆ Activity 2.4 — Base + Metal → Hydrogen Gas
Materials: Granulated zinc, NaOH solution.
Procedure: Add NaOH solution to zinc metal, warm gently. Test evolved gas by burning.
Observations: Hβ gas is evolved (pops near flame), just like with acids.
Conclusion: Bases can also react with certain metals (Zn, Al) to evolve Hβ. Equation: 2NaOH(aq) + Zn(s) → NaβZnOβ(s) + Hβ(g) [sodium zincate formed]. Not all metals react this way.
βΆ Activity 2.5 — Acid + Carbonate/Bicarbonate → COβ
Materials: NaβCOβ (test tube A), NaHCOβ (test tube B), dilute HCl, lime water (Ca(OH)β solution).
Procedure: Add HCl to each test tube. Pass evolved gas through lime water.
Observations: Brisk effervescence (COβ) in both tubes. Lime water turns milky white (CaCOβ precipitate). On passing excess COβ, milkiness disappears (Ca(HCOβ)β forms — soluble).
Equations: NaβCOβ + 2HCl → 2NaCl + HβO + COβ; NaHCOβ + HCl → NaCl + HβO + COβ; Ca(OH)β + COβ → CaCOβ↓ + HβO
βΆ Activity 2.6 — Neutralisation (Acid + Base)
Materials: NaOH solution, HCl solution, phenolphthalein indicator.
Procedure: Add phenolphthalein to NaOH (turns pink). Add HCl drop by drop. Observe colour change. Then add NaOH back.
Observations: NaOH + phenolphthalein = pink. Adding HCl makes it colourless (acid neutralises base). Adding NaOH again restores pink colour.
Conclusion: Acid and base neutralise each other. NaOH + HCl → NaCl + HβO. At endpoint (neutral), phenolphthalein is colourless.
βΆ Activity 2.7 — Metal Oxide + Acid
Materials: Copper oxide (CuO, black powder), dilute HCl, beaker.
Procedure: Add dilute HCl slowly to CuO while stirring.
Observations: Black CuO dissolves. Solution turns blue-green (copper chloride CuClβ formed).
Conclusion: Metallic oxides are basic oxides — they react with acids to form salt + water, just like bases. CuO + 2HCl → CuClβ + HβO. Non-metallic oxides (COβ) react with bases and are acidic oxides.
βΆ Activity 2.8 — Electrical Conductivity: Acids vs Glucose/Alcohol
Materials: HCl solution, HβSOβ solution, glucose solution, alcohol solution, 6V battery, bulb, two nails in cork.
Procedure: Pour each solution into beaker. Connect nails to battery through bulb. Observe whether bulb glows.
Observations: Bulb glows with HCl and HβSOβ. Bulb does NOT glow with glucose and alcohol.
Conclusion: Acids produce ions (HβΊ and anions) in water which conduct electricity. Glucose/alcohol do not produce ions — hence not acidic despite containing hydrogen.
βΆ Activity 2.9 — Dry HCl vs Wet HCl: Need for Water
Materials: Solid NaCl, concentrated HβSOβ, dry and wet blue litmus paper.
Procedure: Add conc. HβSOβ to NaCl. Pass gas through dry litmus, then wet litmus.
Observations: Dry HCl gas does NOT change dry litmus. Moist/wet litmus paper turns red.
Conclusion: HCl gas is not acidic in the absence of water. HβΊ ions form ONLY in the presence of water: HCl + HβO → HβOβΊ + Clβ». Water is essential for ionisation and acidic behaviour.
βΆ Activity 2.10 — Dilution of Acids/Bases: Exothermic Process
Materials: Water (10 mL), concentrated HβSOβ, NaOH pellets, beaker.
Procedure: Add a few drops of conc. HβSOβ to water (NOT the other way). Touch base of beaker. Repeat with NaOH pellets.
Observations: The beaker becomes very hot — dissolving is highly exothermic for both acid and base.
Safety conclusion: Always add ACID to WATER. If water is added to acid, heat generated can cause the mixture to splash, causing burns. Dilution decreases HβOβΊ/OHβ» concentration per unit volume.
βΆ Activity 2.11 — Measuring pH of Common Solutions
Materials: Various solutions (saliva, lemon juice, cola, carrot juice, coffee, tomato juice, tap water, NaOH, HCl), universal indicator paper.
Procedure: Test pH of each solution using universal indicator paper.
Expected results: Gastric juice ~1.2, lemon ~2–3, cola ~3, coffee ~5, pure water ~7, sea water ~8, milk of magnesia ~10, NaOH ~14.
Conclusion: pH paper gives approximate pH values. Neutral = 7, acidic <7, basic >7.
βΆ Activity 2.12 — Soil pH Test
Materials: Soil samples from various locations, water, test tube, universal indicator paper.
Procedure: Add 5 mL water to 2g soil, shake, filter, test filtrate pH with universal indicator paper.
Conclusion: Different soils have different pH values. Plants need specific pH for healthy growth. Acidic soil can be treated with quick lime, slaked lime or chalk (all alkaline) to neutralise the acidity.
βΆ Activity 2.13 — Family of Salts
Task: Write formulae of: KβSOβ, NaβSOβ, CaSOβ, MgSOβ, CuSOβ, NaCl, NaNOβ, NaβCOβ, NHβCl. Identify families.
Sulphate family: KβSOβ, NaβSOβ, CaSOβ, MgSOβ, CuSOβ (share SOβ²β»).
Sodium family: NaβSOβ, NaCl, NaNOβ, NaβCOβ (share NaβΊ).
Chloride family: NaCl, NHβCl (share Clβ»).
Conclusion: Salts with the same positive or negative radical belong to the same family.
βΆ Activity 2.14 — pH of Salt Solutions
Materials: Various salts, distilled water, litmus, pH paper.
Test: Dissolve NaCl, KNOβ, AlClβ, ZnSOβ, CuSOβ, CHβCOONa, NaβCOβ, NaHCOβ in distilled water. Test with litmus and pH paper.
Results: NaCl, KNOβ = neutral (pH 7). AlClβ, ZnSOβ, CuSOβ = acidic (pH <7, strong acid + weak base). NaβCOβ, NaHCOβ, CHβCOONa = basic (pH >7, weak acid + strong base).
Conclusion: The pH of a salt solution depends on the relative strengths of the acid and base from which it was formed.
βΆ Activity 2.15 — Water of Crystallisation (CuSOβ)
Materials: CuSOβ·5HβO crystals, dry boiling tube, burner, water dropper.
Procedure: Heat crystals. Observe colour change and water droplets in tube. Add 2–3 drops of water to cooled anhydrous CuSOβ.
Observations: Blue crystals turn white on heating. Water droplets condense on cool upper tube. Adding water to white powder restores blue colour.
Conclusion: CuSOβ·5HβO contains 5 water molecules of crystallisation. Heating removes them (anhydrous CuSOβ = white). Adding water hydrates it back. This confirms water of crystallisation.
EXAMPLE 1
Write the balanced equation for dilute HβSOβ reacting with zinc granules. Identify the type of reaction.
Show Solution βΆ
Word equation: Zinc + Sulphuric acid → Zinc sulphate + Hydrogen
Balanced: Zn(s) + HβSOβ(aq) → ZnSOβ(aq) + Hβ(g)
Check: Zn=1=1β, H=2=2β, S=1=1β, O=4=4β
Type: Displacement reaction (Zn displaces H from acid). Also produces Hβ gas — test: burns with pop sound.
EXAMPLE 2
Why does the colour of phenolphthalein change from pink to colourless when HCl is added to NaOH solution?
Show Solution βΆ
NaOH is basic (produces OHβ» ions) → phenolphthalein turns PINK in basic medium. When HCl is added, the acid and base neutralise each other: NaOH + HCl → NaCl + HβO. The OHβ» ions are consumed. The solution becomes neutral (or acidic if excess HCl). Phenolphthalein is colourless in neutral and acidic solutions → colour disappears. Adding NaOH again restores basicity → pink reappears.
EXAMPLE 3
Why do HCl and HβSOβ show acidic properties in water but dry HCl gas does not?
Show Solution βΆ
Acidic behaviour is caused by HβΊ(aq) ions. HβΊ ions cannot exist alone — they require water molecules to form HβOβΊ (hydronium ions): HCl + HβO → HβOβΊ + Clβ». In dry HCl gas, there is no water present. So no ionisation occurs, no HβΊ ions are produced, and dry litmus paper does not change colour. Only in the presence of water does HCl dissociate and show acidic behaviour.
EXAMPLE 4
Five solutions have pH values 4, 1, 11, 7, 9. Identify each. Arrange in increasing order of HβΊ concentration.
Show Solution βΆ
pH 1 = strongly acidic | pH 4 = weakly acidic | pH 7 = neutral | pH 9 = weakly alkaline | pH 11 = strongly alkaline.
Increasing HβΊ concentration means decreasing pH, so order: pH 11 → pH 9 → pH 7 → pH 4 → pH 1 (i.e., least HβΊ at pH 11, most HβΊ at pH 1).
EXAMPLE 5
Explain the chlor-alkali process. Why is it called ‘chlor-alkali’?
Show Solution βΆ
When electricity is passed through aqueous NaCl (brine): 2NaCl(aq) + 2HβO(l) → 2NaOH(aq) + Clβ(g) + Hβ(g)
It is called chlor-alkali because: “Chlor” refers to chlorine gas produced at the anode. “Alkali” refers to sodium hydroxide (an alkali) produced near the cathode. Three useful products: Clβ (water treatment, PVC), Hβ (fuel, fertilisers), NaOH (soaps, detergents, paper).
EXAMPLE 6
Metal compound A reacts with dilute HCl to produce effervescence. Gas extinguishes a burning candle. One product is CaClβ. Write the balanced equation.
Show Solution βΆ
Gas extinguishes a burning candle → it is COβ (not Hβ, which burns). COβ is produced by acid + carbonate/bicarbonate. Product is CaClβ → Ca is involved. Compound A = CaCOβ (calcium carbonate).
Balanced equation: CaCOβ(s) + 2HCl(aq) → CaClβ(aq) + HβO(l) + COβ(g)
Ca=1=1β, C=1=1β, O=3=3β, H=2=2β, Cl=2=2β
EXAMPLE 7
Why should curd and sour substances not be kept in brass or copper vessels?
Show Solution βΆ
Curd and sour substances contain acids (lactic acid, citric acid). Acids react with metals (brass contains copper and zinc; copper vessels are copper). The reaction produces metal salts which contaminate the food and may be harmful. Also, the metal is corroded, ruining the vessel. This is why acidic foods should be stored in glass, ceramic or food-grade stainless steel containers.
EXAMPLE 8
Fresh milk has pH 6. What happens to pH as it turns to curd? Why?
Show Solution βΆ
As milk turns to curd, bacteria convert lactose (milk sugar) into lactic acid. As lactic acid is produced, the concentration of HβΊ ions increases. pH decreases (becomes more acidic, pH drops below 6). This explains the sour taste of curd. The lower pH also helps preserve the curd temporarily by inhibiting harmful bacterial growth.
EXAMPLE 9
A milkman adds a small amount of baking soda to fresh milk. (a) Why does he shift the pH to slightly alkaline? (b) Why does this milk take longer to set as curd?
Show Solution βΆ
(a) Baking soda (NaHCOβ) is a mild base. Making milk slightly alkaline (pH slightly above 7) provides a buffer against souring. When milk starts turning sour (lactic acid forms), the base first neutralises the acid before pH drops. This delays souring and extends shelf life.
(b) For milk to set as curd (coagulate), the pH must fall sufficiently (bacteria need acidic environment to grow and produce enough lactic acid). Since baking soda keeps neutralising the acid produced, it takes longer for the pH to fall to the level needed for curd formation.
EXAMPLE 10
Why is Plaster of Paris stored in moisture-proof containers?
Show Solution βΆ
Plaster of Paris (CaSOβ·½HβO) reacts with water to form gypsum (CaSOβ·2HβO), a hard crystalline solid:
CaSOβ·½HβO + 1½HβO → CaSOβ·2HβO (sets hard)
If exposed to moisture in the air, it will absorb water and set into hard gypsum even before use — making it completely useless. Moisture-proof storage keeps it dry and ready to use.
EXAMPLE 11
Equal lengths of Mg ribbon in HCl (tube A) and CHβCOOH (tube B) — same concentration. Which tube fizzes more vigorously and why?
Show Solution βΆ
Test tube A (HCl) fizzes more vigorously. HCl is a strong acid — it completely ionises in water to produce a large concentration of HβΊ ions. CHβCOOH is a weak acid — it only partially ionises, producing fewer HβΊ ions at the same concentration. Since the reaction rate depends on HβΊ ion concentration, HCl reacts faster and produces Hβ gas more vigorously.
Reactions: Mg + 2HCl → MgClβ + Hβ↑ | Mg + 2CHβCOOH → (CHβCOO)βMg + Hβ↑
EXAMPLE 12
10 mL NaOH is completely neutralised by 8 mL HCl. If 20 mL of same NaOH is taken, how much HCl is needed?
Show Solution βΆ
10 mL NaOH requires 8 mL HCl.
Ratio: NaOH : HCl = 10 : 8 = 5 : 4
For 20 mL NaOH: HCl required = (8/10) × 20 = 16 mL
Answer: (d) 16 mL. Since the NaOH solution amount doubled (10→20 mL), the HCl required also doubles (8→16 mL).
EXAMPLE 13
Write balanced equations for: (a) dil. HβSOβ + Al; (b) dil. HCl + Fe filings; (c) NaHCOβ heated.
Show Solution βΆ
(a) 3HβSOβ(dil) + 2Al(s) → Alβ(SOβ)β(aq) + 3Hβ(g) — Al=2=2β, S=3=3β, H=6=6β
(b) 2HCl(aq) + Fe(s) → FeClβ(aq) + Hβ(g) — Fe=1=1β, H=2=2β, Cl=2=2β
(c) 2NaHCOβ(s) →Heat NaβCOβ(s) + HβO(l) + COβ(g) — Na=2=2β, H=2=2β, C=2=2β, O=6=6β
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π Practice Set A — Multiple Choice Questions (8 Questions) |
Q1. A solution turns red litmus blue. Its pH is likely to be:
(a) 1 (b) 4 (c) 5 (d) 10
Show Answer βΆ
(d) 10 — A substance that turns red litmus blue is basic (alkaline). Basic solutions have pH greater than 7. Among the options, only pH 10 > 7.
Q2. A solution reacts with crushed egg shells to give a gas that turns lime-water milky. The solution contains:
(a) NaCl (b) HCl (c) LiCl (d) KCl
Show Answer βΆ
(b) HCl — Egg shells are CaCOβ. An acid reacts with a carbonate to produce COβ, which turns lime water milky. Of the options, only HCl is an acid. NaCl, LiCl, KCl are salts and won’t react with CaCOβ.
Q3. Which medicine is used for treating indigestion (excess stomach acid)?
(a) Antibiotic (b) Analgesic (c) Antacid (d) Antiseptic
Show Answer βΆ
(c) Antacid — Antacids (like Milk of Magnesia/Mg(OH)β) are mild bases that neutralise excess HCl in the stomach: Mg(OH)β + 2HCl → MgClβ + 2HβO. Antibiotics kill bacteria; analgesics relieve pain; antiseptics kill germs on surfaces.
Q4. Water of crystallisation in copper sulphate (CuSOβ·5HβO) is:
(a) 1 molecule (b) 2 molecules (c) 5 molecules (d) 10 molecules
Show Answer βΆ
(c) 5 molecules — The formula CuSOβ·5HβO indicates 5 water molecules per formula unit. These are the water of crystallisation. When heated, these 5 molecules are lost and white anhydrous CuSOβ remains.
Q5. pH of acid rain is:
(a) exactly 7 (b) above 7 (c) less than 5.6 (d) between 6 and 7
Show Answer βΆ
(c) Less than 5.6 — Normal rain water has pH ~5.6 (slightly acidic due to dissolved COβ forming carbonic acid). When SOβ and NOβ from burning fossil fuels dissolve in rain, pH falls below 5.6 — this is acid rain.
Q6. Bleaching powder is produced by the action of chlorine on:
(a) Dry NaCl (b) Dry NaOH (c) Dry slaked lime Ca(OH)β (d) Quick lime CaO
Show Answer βΆ
(c) Dry slaked lime Ca(OH)β — Reaction: 2Ca(OH)β + 2Clβ → Ca(ClO)β + CaClβ + 2HβO. The key word is “dry” slaked lime — if Ca(OH)β is wet, the product differs. Bleaching powder formula: Ca(ClO)β.
Q7. Why does distilled water not conduct electricity but rain water does?
(a) Rain water is basic (b) Rain water contains dissolved ions from gases (c) Rain water is a mixture (d) Distilled water is denser
Show Answer βΆ
(b) Rain water contains dissolved ions from gases — COβ dissolves in rain to form HβCOβ, which ionises: HβCOβ → HβΊ + HCOββ». These ions carry electrical current. Distilled water is pure HβO with no ions, so it cannot conduct electricity.
Q8. The common name of Ca(ClO)β is:
(a) Baking soda (b) Washing soda (c) Bleaching powder (d) Plaster of Paris
Show Answer βΆ
(c) Bleaching powder — Ca(ClO)β is calcium hypochlorite / bleaching powder. Baking soda = NaHCOβ. Washing soda = NaβCOβ·10HβO. Plaster of Paris = CaSOβ·½HβO.
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π Practice Set B — Short Answer Questions (6 Questions) |
Q1. What is a neutralisation reaction? Give two examples with equations.
Show Answer βΆ
A neutralisation reaction is the reaction between an acid and a base to form a salt and water. The acid and base neutralise each other’s effect: Acid + Base → Salt + Water.
Example 1: NaOH(aq) + HCl(aq) → NaCl(aq) + HβO(l)
Example 2: Ca(OH)β(aq) + HβSOβ(aq) → CaSOβ(aq) + 2HβO(l)
Q2. What is water of crystallisation? How does heating affect copper sulphate crystals?
Show Answer βΆ
Water of crystallisation is the fixed number of water molecules that are chemically combined with one formula unit of a crystalline salt. CuSOβ·5HβO has 5 water molecules of crystallisation. On heating, these molecules are driven off: CuSOβ·5HβO →Heat CuSOβ + 5HβO. Blue crystals turn white (anhydrous CuSOβ). Adding water again: white powder turns blue — water of crystallisation is restored.
Q3. Give two important uses each of baking soda and washing soda.
Show Answer βΆ
Baking soda (NaHCOβ): (1) Making baking powder — COβ released makes bread/cake spongy. (2) Antacid — neutralises excess stomach acid; also used in soda-acid fire extinguishers.
Washing soda (NaβCOβ·10HβO): (1) Used in glass, soap, paper industries. (2) Removes permanent hardness of water; used as a cleaning agent at home.
Q4. Why do solutions of bases in water conduct electricity?
Show Answer βΆ
When a base dissolves in water, it ionises to produce hydroxide ions (OHβ») and metal cations: NaOH → NaβΊ + OHβ». These ions (charged particles) move freely in the solution and carry electric current, enabling electrical conduction. Pure water (with no ions) does not conduct electricity. The more the base ionises, the better it conducts electricity (strong bases conduct better than weak bases).
Q5. What are olfactory indicators? Name two olfactory indicators and describe how they work.
Show Answer βΆ
Olfactory indicators are substances whose smell (odour) changes when they come into contact with acidic or basic solutions — they detect acid/base through change in smell rather than colour change.
Onion: Strong onion smell is present in acid but disappears in base (NaOH destroys the odour-producing compounds). Vanilla: Pleasant vanilla smell disappears in basic solution. Both onion and vanilla are used as olfactory indicators when colour changes cannot be observed (e.g., in coloured solutions or for visually impaired students).
Q6. How is the pH of the mouth related to tooth decay? How can it be prevented?
Show Answer βΆ
Bacteria in the mouth break down sugars and food particles left after eating to produce acids. When the pH of the mouth drops below 5.5, the acid corrodes the tooth enamel (calcium hydroxyapatite). This is the beginning of tooth decay (dental caries).
Prevention: (1) Clean mouth/brush teeth after meals to remove food particles and acids. (2) Use basic toothpaste — the base neutralises the acids formed by bacteria: Acid + Base → Salt + Water. This raises pH above 5.5, preventing enamel corrosion.
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π Practice Set C — Long Answer Questions (4 Questions) |
Q1. What is the pH scale? Explain the importance of pH in four aspects of everyday life.
Show Answer βΆ
The
pH scale (0–14) measures hydrogen ion (HβΊ) concentration. pH 7 = neutral; <7 = acidic; >7 = basic. Higher HβΊ → lower pH. A universal indicator shows different colours at different pH values.
1. Human Body: Body functions best at pH 7.0–7.8. Blood pH is ~7.4. Even slight changes can be fatal. Living organisms survive only within a narrow pH range.
2. Digestion: Stomach produces HCl (pH ~1.2) to digest food. Excess acid causes indigestion. Antacids (mild bases) neutralise excess acid and provide relief.
3. Tooth Decay: Bacteria produce acid from sugar. When mouth pH < 5.5, tooth enamel corrodes. Basic toothpaste neutralises acid and prevents decay.
4. Agriculture: Plants need specific pH for growth. Acidic soil (due to acid rain or chemical fertilisers) is treated with lime (CaO or Ca(OH)β) to raise pH.
Q2. Describe all the chemical reactions of acids (with metals, carbonates, bases, metallic oxides). Give one example equation for each.
Show Answer βΆ
1. Acid + Metal → Salt + Hβ: Acids displace hydrogen from metals. Zn + HβSOβ → ZnSOβ + Hβ↑ [Hβ burns with pop]
2. Acid + Metal Carbonate → Salt + COβ + HβO: NaβCOβ + 2HCl → 2NaCl + HβO + COβ↑ [COβ turns lime water milky]
3. Acid + Metal Hydrogencarbonate → Salt + COβ + HβO: NaHCOβ + HCl → NaCl + HβO + COβ↑
4. Acid + Base (Neutralisation) → Salt + HβO: NaOH + HCl → NaCl + HβO [pH 7 at endpoint]
5. Acid + Metal Oxide → Salt + HβO: CuO + 2HCl → CuClβ + HβO [black CuO → blue-green CuClβ solution]. Metallic oxides are basic oxides.
Q3. Explain the preparation, chemical formula, and uses of: (a) Bleaching powder; (b) Baking soda; (c) Washing soda.
Show Answer βΆ
(a) Bleaching Powder Ca(ClO)β: Clβ gas acts on dry slaked lime: 2Ca(OH)β + 2Clβ → Ca(ClO)β + CaClβ + 2HβO. Uses: bleaching cotton/linen/paper/washed clothes; oxidising agent in industries; disinfecting drinking water.
(b) Baking Soda NaHCOβ: NaCl + HβO + COβ + NHβ → NHβCl + NaHCOβ. Mild non-corrosive basic salt. Uses: baking powder (COβ makes bread spongy: 2NaHCOβ →Heat NaβCOβ + HβO + COβ); antacid (neutralises excess stomach acid); soda-acid fire extinguisher.
(c) Washing Soda NaβCOβ·10HβO: Heat NaHCOβ → NaβCOβ; add water: NaβCOβ + 10HβO → NaβCOβ·10HβO. Uses: glass, soap, paper industries; manufacture of sodium compounds like borax; domestic cleaning agent; removes permanent hardness of water.
Q4. What are strong and weak acids? How does the activity of an acid depend on ionisation? Compare HCl and CHβCOOH at the same concentration.
Show Answer βΆ
Strong acids completely ionise in water to produce a large number of HβΊ ions: HCl → HβΊ + Clβ» (complete). Strong acids: HCl, HβSOβ, HNOβ.
Weak acids partially ionise: CHβCOOH β CHβCOOβ» + HβΊ (partial). Weak acids: CHβCOOH, HβCOβ, HβPOβ.
Comparison: At the same molar concentration (e.g., 1M): 1M HCl has many more HβΊ ions than 1M CHβCOOH. HCl has a lower pH and reacts more vigorously with metals (Mg ribbon fizzes more in HCl). HCl conducts electricity better (more ions). The activity and reactivity of an acid directly depends on the concentration of HβΊ ions in solution — more HβΊ = more reactive/stronger acid.
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π Practice Set D — Numerical / Equation Problems (4 Questions) |
Q1. Write balanced equations for: (a) dil. HCl + Mg ribbon; (b) dil. HβSOβ + aluminium powder.
Show Answer βΆ
(a) Mg(s) + 2HCl(aq) → MgClβ(aq) + Hβ(g) — Mg=1=1β, H=2=2β, Cl=2=2β. Displacement reaction; Hβ burns with pop.
(b) 2Al(s) + 3HβSOβ(aq) → Alβ(SOβ)β(aq) + 3Hβ(g) — Al=2=2β, H=6=6β, S=3=3β, O=12=12β. Displacement reaction; Hβ evolved.
Q2. Write the equation for heating baking soda. What gas is produced? How would you test for it?
Show Answer βΆ
2NaHCOβ(s) →Heat NaβCOβ(s) + HβO(l) + COβ(g)
Na=2=2β, H=2=2β, C=2=2β, O=6=6β
Gas produced: COβ (carbon dioxide).
Test: Pass the gas through calcium hydroxide (lime water) — Ca(OH)β(aq) + COβ(g) → CaCOβ(s)↓ + HβO(l). Lime water turns milky white → confirms COβ. On passing excess COβ, white precipitate dissolves again (Ca(HCOβ)β forms).
Q3. Write the reaction between Plaster of Paris and water. Why is it called Plaster of ‘Paris’?
Show Answer βΆ
CaSOβ·½HβO + 1½HβO → CaSOβ·2HβO (Gypsum)
Plaster of Paris (white powder) absorbs water and sets into hard gypsum. This setting is irreversible — that is why it must be stored in moisture-proof containers.
It is called “Plaster of Paris” because large deposits of gypsum are found near Paris, France. The plaster was historically made there from local gypsum deposits, giving it the name.
Q4. Solution A has pH 6, Solution B has pH 8. (a) Which has more HβΊ? (b) Which is acidic/basic? (c) If B is diluted, what happens to its pH?
Show Answer βΆ
(a) Solution A (pH 6) has more HβΊ ions — Lower pH means higher HβΊ concentration. pH and HβΊ are inversely related.
(b) Solution A (pH 6) is acidic (pH <7) — could be urine or milk. Solution B (pH 8) is basic/alkaline (pH >7) — could be sea water or egg white.
(c) If Solution B (basic) is diluted, water is added, which decreases OHβ» concentration per unit volume. pH decreases (moves towards 7, neutral). Dilution of a basic solution moves its pH towards 7.
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π‘ Important Facts to Remember |
β‘ Acid + Metal Carbonate vs Acid + Metal: The gas produced is different — carbonates give COβ (extinguishes candle, turns lime water milky), metals give Hβ (burns with pop). Don’t confuse these tests!
β‘ Litmus — Origin: Litmus is extracted from Thallophyta (lichen). When neutral: purple. In acid: red. In base: blue. Turmeric is another natural indicator (yellow in acid/neutral → reddish-brown in base).
β‘ Lime Water Test: Ca(OH)β + COβ → CaCOβ↓ + HβO (turns milky). Excess COβ: CaCOβ + HβO + COβ → Ca(HCOβ)β (milkiness disappears — soluble bicarbonate).
β‘ Baking Powder vs Baking Soda: Baking soda = NaHCOβ alone. Baking powder = NaHCOβ + a mild edible acid (tartaric acid). When heated or wetted: NaHCOβ + HβΊ → COβ + HβO + salt. COβ makes baked goods light and spongy.
Chapter 2 — Acids, Bases and Salts: Key Points
Acids Sour taste • Turn blue litmus red • pH <7 • Produce HβΊ(aq)/HβOβΊ in water • React with metals → Hβ • React with carbonates → COβ • React with bases → salt + water |
Bases/Alkalis Bitter taste • Soapy feel • Turn red litmus blue • pH >7 • Produce OHβ»(aq) in water • React with metals (Zn, Al) → Hβ • Alkalis = water-soluble bases |
pH Scale 0–14 range • pH 7 = neutral • pH <7 = acidic • pH >7 = alkaline • Universal indicator shows colours • HβΊ ↑ = pH ↓ |
Salts Strong acid + Strong base → neutral salt (pH 7) • Strong acid + Weak base → acidic salt • Weak acid + Strong base → basic salt |
| Important Chemical |
Formula |
Made From |
Key Use |
| Bleaching powder |
Ca(ClO)β |
Clβ + Ca(OH)β |
Bleaching, disinfection |
| Baking soda |
NaHCOβ |
NaCl + COβ + NHβ |
Baking, antacid, fire extinguisher |
| Washing soda |
NaβCOβ·10HβO |
Heat NaHCOβ + recrystallise |
Glass, soap, paper; hard water |
| Plaster of Paris |
CaSOβ·½HβO |
Heat gypsum at 373K |
Fractured bones, toys, decor |
| Sodium hydroxide |
NaOH |
Chlor-alkali process (electrolysis of brine) |
Soaps, detergents, paper |
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π 8-Point Exam Quick-Check |
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β
Must-Know Facts
1. All acids produce HβΊ(aq) in water; all bases produce OHβ»(aq). Water is essential for ionisation.
2. Neutralisation: HβΊ(aq) + OHβ»(aq) → HβO(l). Salt and water formed.
3. Chlor-alkali process gives three products: Clβ (anode), Hβ (cathode), NaOH (near cathode).
4. Tooth decay starts at pH < 5.5. Acid rain pH < 5.6. Body works at pH 7.0–7.8.
5. COβ test = lime water turns milky. Hβ test = burns with pop sound.
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β Common Exam Traps
Trap 1: All alkalis are bases but NOT all bases are alkalis (only water-soluble ones).
Trap 2: Dry HCl does NOT show acidic behaviour — water is essential for ionisation.
Trap 3: Always add acid TO water (A to W), never water to acid — risk of splash/burns.
Trap 4: Glucose and alcohol contain H but are NOT acids — they don’t produce HβΊ in water.
Trap 5: Higher pH does NOT mean more HβΊ — it means LESS HβΊ (inverse relationship).
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