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Chapter 2: Acids, Bases and Salts

Grade 10 Science  ·  CBSE / NCERT  ·  Chapter 2

Acids, Bases
and Salts

From the tang of lemon to the sting of bee venom — explore the chemistry of acids, bases, salts, the pH scale, neutralisation, and essential everyday chemical products.

🧪 Acids & Bases 📊 pH Scale ⚗ Neutralisation 🏭 Salts & Industry

  📋 Chapter at a Glance
Section Topics Covered Key Terms
2.1 Chemical Properties Acids/bases in lab, reactions with metals, metal carbonates, hydrogencarbonates, neutralisation, metallic & non-metallic oxides Indicator, Olfactory indicator, Neutralisation, Salt, Basic oxide, Acidic oxide
2.2 Common Properties H⁺ ions in acids, OH⁻ ions in bases, ionisation in water, dilution, exothermic dissolution, strong vs weak acids/bases H⁺(aq), Hydronium ion H₃O⁺, OH⁻(aq), Alkali, Dilution, Ionisation
2.3 pH Scale Universal indicator, pH 0–14, importance of pH in everyday life, acid rain, tooth decay, digestive system pH, Universal indicator, Acid rain, Antacid, Strong acid, Weak acid
2.4 More About Salts Family of salts, pH of salts, chlor-alkali process, bleaching powder, baking soda, washing soda, water of crystallisation, Plaster of Paris Brine, Chlor-alkali, NaHCO₃, Na₂CO₃, Water of crystallisation, Gypsum, Plaster of Paris

  🔑 Key Definitions
Acid: A substance that produces hydrogen ions (H⁺) or hydronium ions (H₃O⁺) when dissolved in water. Acids are sour in taste, turn blue litmus red, and have pH less than 7. Examples: HCl, H₂SO₄, HNO₃, CH₃COOH.
Base: A substance that produces hydroxide ions (OH⁻) when dissolved in water. Bases are bitter in taste, soapy to touch, turn red litmus blue, and have pH more than 7. Examples: NaOH, Ca(OH)₂, KOH, Mg(OH)₂.
Alkali: A base that is soluble in water. All alkalis are bases, but not all bases are alkalis. Alkalis are soapy to touch, bitter and corrosive. Examples: NaOH, KOH, Ca(OH)₂ dissolved in water.
Indicator: A substance that shows different colours in acidic and basic solutions, used to detect whether a substance is an acid or a base. Examples: litmus (natural), phenolphthalein and methyl orange (synthetic).
Olfactory Indicator: A substance whose odour changes in acidic or basic medium. Examples: onion (loses smell in base), vanilla (loses smell in base), clove oil (loses smell in acid).
Neutralisation Reaction: The reaction between an acid and a base to form a salt and water. The acid and base neutralise each other’s effects. General form: Acid + Base → Salt + Water. At the ionic level: H⁺(aq) + OH⁻(aq) → H₂O(l).
Salt: An ionic compound formed when the hydrogen of an acid is replaced by a metal (or ammonium). Salts are formed in neutralisation reactions between acids and bases. Example: NaCl (common salt) from HCl + NaOH.
pH Scale: A scale (0 to 14) that measures the concentration of hydrogen ions in a solution. pH 7 = neutral; pH < 7 = acidic; pH > 7 = basic/alkaline. The ‘p’ in pH stands for ‘potenz’ (German for power). Higher H⁺ concentration = lower pH.
Strong Acid: An acid that completely ionises in water to produce a large number of H⁺ ions. Examples: HCl, H₂SO₄, HNO₃. A weak acid only partially ionises — e.g., CH₃COOH (acetic acid).
Water of Crystallisation: The fixed number of water molecules present in one formula unit of a crystalline salt. Example: CuSO₄·5H₂O has 5 water molecules. When heated, these water molecules are lost and the colour changes (blue CuSO₄ turns white).
Plaster of Paris: Calcium sulphate hemihydrate (CaSO₄·½H₂O), obtained by heating gypsum (CaSO₄·2H₂O) at 373K. On mixing with water, it sets into a hard solid (gypsum). Used for fractured bones, toys, smooth surfaces.
Chlor-alkali Process: The electrolysis of brine (aqueous NaCl) which produces three useful products: chlorine gas (at anode), hydrogen gas (at cathode), and sodium hydroxide solution (near cathode). Reaction: 2NaCl(aq) + 2H₂O(l) → 2NaOH(aq) + Cl₂(g) + H₂(g).

  2.1 — Chemical Properties of Acids and Bases

Acids and bases have been known since ancient times — acids for their sour taste and bases for their bitter taste and soapy feel. However, we never taste chemicals directly in the laboratory. Instead, we use indicators to test them. Litmus (extracted from lichen, a plant in the Thallophyta division) is the most common natural indicator — it turns red in acid and blue in base.

  📐 Diagram 1: Indicator Colour Chart
Indicator In Acid In Base In Neutral
Blue Litmus Turns RED Stays BLUE Stays Blue
Red Litmus Stays RED Turns BLUE Stays Red
Phenolphthalein Colourless PINK/Red Colourless
Methyl Orange RED/Pink YELLOW Orange
Turmeric Yellow Reddish-brown Yellow

  2.1.2 — How do Acids and Bases React with Metals?

When acids react with metals, they displace hydrogen gas and form a salt. When bases (like NaOH) react with certain metals (like zinc, aluminium), they also produce hydrogen gas along with a salt. The hydrogen burns with a ‘pop’ sound — the test for H₂ gas.

  📐 Diagram 2: Zinc + Dilute Sulphuric Acid (Activity 2.3)
Delivery tube
H₂ gas bubbles ↑

Dilute H₂SO₄
•••••
Zn granules

Reactions:

Acid + Metal → Salt + H₂ gas

Zn + H₂SO₄ → ZnSO₄ + H₂↑
Zn + 2HCl → ZnCl₂ + H₂↑
Mg + 2HCl → MgCl₂ + H₂↑

Base + Metal → Salt + H₂:
2NaOH + Zn → Na₂ZnO₂ + H₂↑
(Sodium zincate)

Test for H₂: Burns with a pop sound when candle brought near.

  2.1.3 — Metal Carbonates and Hydrogencarbonates with Acids

All metal carbonates and hydrogencarbonates react with acids to produce a salt, carbon dioxide gas and water. The CO₂ gas produced turns lime water milky — this is the standard test for CO₂.

Metal carbonate / Hydrogencarbonate + Acid → Salt + CO₂ + Water
  📐 Diagram 3: CO₂ passed through Lime Water (Activity 2.5)
Test Tube A
Na₂CO₃ + HCl
→ CO₂ gas
Lime Water
Ca(OH)₂(aq)
clear initially
Turns MILKY WHITE
CaCO₃↓ precipitate!
Equations: Na₂CO₃(s) + 2HCl(aq) → 2NaCl(aq) + H₂O(l) + CO₂(g)
NaHCO₃(s) + HCl(aq) → NaCl(aq) + H₂O(l) + CO₂(g)
Ca(OH)₂(aq) + CO₂(g) → CaCO₃(s)↓ + H₂O(l) [White precipitate = test for CO₂]
Excess CO₂: CaCO₃(s) + H₂O(l) + CO₂(g) → Ca(HCO₃)₂(aq) [Soluble — milkiness disappears]

  2.1.4 — Neutralisation (Acid + Base)

When an acid and a base react together, they neutralise each other’s effect to form a salt and water. This is called a neutralisation reaction. Phenolphthalein (pink in base, colourless in acid) is used to detect the endpoint.

General Reaction:
Acid + Base → Salt + Water
HX + MOH → MX + H₂O
At ionic level:
H⁺(aq) + OH⁻(aq) → H₂O(l)

Example:
NaOH(aq) + HCl(aq) → NaCl(aq) + H₂O(l)

  Metal Oxide + Acid (similar to neutralisation):
Metal oxide + Acid → Salt + Water
CuO(s) + 2HCl(aq) → CuCl₂(aq) + H₂O(l)
(Black CuO dissolves → Blue-green CuCl₂)

Metallic oxides are basic oxides.
Non-metallic oxides (e.g., CO₂, SO₂) are acidic oxides.

  2.2 — What do All Acids and All Bases Have in Common?

Although glucose and alcohol also contain hydrogen, they are not acids. The key is whether hydrogen ions (H⁺) are produced in water. Acids dissolve in water to produce H⁺(aq) ions — these carry electric current, making the bulb glow in Activity 2.8. Glucose and alcohol don’t produce ions, so the bulb does NOT glow with them.

Substance Contains H? Produces H⁺ in water? Bulb glows? Acidic?
HCl, H₂SO₄, HNO₃ ✓ Yes ✓ Yes ✓ Yes ✓ Yes
Glucose, Alcohol ✓ Yes ✗ No ✗ No ✗ No
  2.2.1 — Acids and Bases in Water: Ionisation

Dry HCl gas does NOT change the colour of dry litmus paper — proving that H⁺ ions are only produced in the presence of water. H⁺ ions cannot exist alone; they combine with water to form the hydronium ion (H₃O⁺).

Acids in water → H⁺(aq) or H₃O⁺
HCl + H₂O → H₃O⁺ + Cl⁻
H₂SO₄ → 2H⁺ + SO₄²⁻
H⁺ + H₂O → H₃O⁺
| Bases in water → OH⁻(aq)
NaOH → Na⁺(aq) + OH⁻(aq)
KOH → K⁺(aq) + OH⁻(aq)
Mg(OH)₂ → Mg²⁺(aq) + 2OH⁻(aq)
⚠ Safety Rule: Always add ACID to WATER (A to W), never water to acid. Dissolving acid in water is highly exothermic — adding water to concentrated acid generates so much heat it can cause splashing and burns!

  2.3 — How Strong are Acid or Base Solutions? The pH Scale

The pH scale (0–14) measures hydrogen ion concentration in a solution. It uses a universal indicator — a mixture of several indicators that shows a different colour for each pH value. The ‘p’ in pH stands for potenz (German: power). Higher H⁺ concentration means lower pH.

  📐 Diagram 4: The pH Scale (0 to 14)
0
Very
Acidic
1
Gastric
juice
2
Lemon
juice
3
Vinegar
Cola
4
Tomato
juice
5
Coffee
Curd
6
Urine
Milk
7
NEUTRAL
Pure Water
8
Sea
water
9
Baking
soda
10
Milk of
magnesia
11
Ammonia
solution
12
Lime
water
13
NaOH
dil.
14
Very
Alkaline
← ACIDIC (H⁺ concentration increasing) N (OH⁻ concentration increasing) BASIC →

  2.3.1 — Importance of pH in Everyday Life
🫀 Human Body

Our body works within pH 7.0–7.8. Slightly alkaline blood (pH ~7.4) is essential. Living organisms can survive only in a narrow pH range. Even a slight change in blood pH can be fatal.

 
🦷 Tooth Decay

Tooth decay starts when mouth pH drops below 5.5. Bacteria produce acids from sugar, corroding tooth enamel (calcium hydroxyapatite). Using basic toothpaste neutralises the acid and prevents decay. Clean teeth after meals!

 
🌧 Acid Rain

When pH of rain water falls below 5.6, it is called acid rain. It is caused by dissolved SO₂ and NO₂ from burning of fossil fuels. Acid rain lowers river pH, making aquatic life survival difficult, and damages buildings and soil.

 
🌱 Soil pH

Plants need a specific pH range for healthy growth. If soil is too acidic, farmers add calcium oxide (quick lime), slaked lime (calcium hydroxide) or chalk (CaCO₃) to neutralise acidity and increase soil pH.

 
🍽 Stomach Acid

The stomach produces HCl (pH ~1.2) to digest food. During indigestion, excess acid causes pain. Antacids (mild bases like Mg(OH)₂ — Milk of magnesia) are used to neutralise excess acid and provide relief.

 
🐝 Animal/Plant Defence

Bee sting injects formic (methanoic) acid — baking soda (base) provides relief. Nettle leaf hairs inject methanoic acid — dock leaf (basic) soothes the pain. Venus atmosphere has H₂SO₄ clouds — hostile to life!

  2.4 — More About Salts

  2.4.2 — pH of Salts
Salt formed from Nature of salt pH Example
Strong acid + Strong base Neutral = 7 NaCl (HCl + NaOH)
Strong acid + Weak base Acidic < 7 NH₄Cl (HCl + NH₄OH)
Weak acid + Strong base Basic > 7 Na₂CO₃ (H₂CO₃ + NaOH)

  2.4.3 — Chemicals from Common Salt (NaCl)

Common salt (sodium chloride, NaCl) — obtained from sea water or rock salt (mined underground) — is a vital raw material for producing many essential chemicals used in industry and daily life.

  📐 Diagram 5: The Chlor-alkali Process
⚡ ELECTRICITY
↓ passed through brine (NaCl solution)
At ANODE (+)
Cl₂ gas evolved
Uses: PVC, disinfectants,
bleaching powder, CFCs
Near CATHODE
NaOH solution
Uses: soap, detergents,
paper, artificial fibres
At CATHODE (−)
H₂ gas evolved
Uses: fuel, margarine,
ammonia for fertilisers
Reaction: 2NaCl(aq) + 2H₂O(l) → 2NaOH(aq) + Cl₂(g) + H₂(g)

🧴 Sodium Hydroxide (NaOH)

From chlor-alkali process. Formed near cathode. Uses: soaps, detergents, paper making, de-greasing metals, artificial fibres.

 
🌊 Bleaching Powder Ca(ClO)₂

Cl₂ on dry slaked lime: 2Ca(OH)₂ + 2Cl₂ → Ca(ClO)₂ + CaCl₂ + 2H₂O. Uses: bleaching textiles/wood pulp/laundry; oxidising agent; disinfecting drinking water.

 
🥖 Baking Soda NaHCO₃

NaCl + H₂O + CO₂ + NH₃ → NH₄Cl + NaHCO₃. Uses: baking powder (CO₂ makes bread spongy); antacid; soda-acid fire extinguisher. Mild non-corrosive basic salt.

 
🫧 Washing Soda Na₂CO₃·10H₂O

Heat NaHCO₃ → Na₂CO₃; recrystallise with water → Na₂CO₃·10H₂O. Uses: glass, soap, paper industries; manufacture of borax; cleaning agent; removes permanent water hardness.

  2.4.4 — Water of Crystallisation & Plaster of Paris
  📐 Diagram 6: Copper Sulphate + Water of Crystallisation (Activity 2.15)
CuSO₄·5H₂O
BLUE crystals
“Hydrated”

HEAT
CuSO₄
WHITE powder
“Anhydrous”

+ few drops H₂O
CuSO₄·5H₂O
BLUE restored!

Water of crystallisation = fixed number of H₂O molecules per formula unit. CuSO₄·5H₂O has 5; Na₂CO₃·10H₂O has 10; CaSO₄·2H₂O (gypsum) has 2.

  📐 Diagram 7: Gypsum → Plaster of Paris → Gypsum
GYPSUM
CaSO₄·2H₂O
White crystalline solid

Heat at 373K
(lose 1.5 H₂O)
PLASTER OF PARIS
CaSO₄·½H₂O
White powder

+ 1½ H₂O
(sets hard)
GYPSUM
CaSO₄·2H₂O
Hard solid mass

Plaster of Paris must be stored in moisture-proof containers — contact with even a little moisture causes it to set into hard gypsum, making it useless.
Uses: fractured bone support, toys, decoration, smooth surfaces. Called “Plaster of Paris” because Paris has large gypsum deposits.

  🌿 Naturally Occurring Acids (Table 2.3)
Natural Source Acid Natural Source Acid
Vinegar Acetic acid (ethanoic acid) Sour milk / Curd Lactic acid
Orange Citric acid Lemon Citric acid
Tamarind Tartaric acid Ant sting Methanoic acid (formic acid)
Tomato Oxalic acid Nettle sting Methanoic acid (formic acid)

  🔬 Activities (2.1 to 2.15) — Lab Experiments
▶ Activity 2.1 — Testing with Indicators
Materials: HCl, H₂SO₄, HNO₃, CH₃COOH, NaOH, Ca(OH)₂, KOH, Mg(OH)₂, NH₄OH; red litmus, blue litmus, phenolphthalein, methyl orange.
Procedure: Put a drop of each solution on a watch-glass. Test with each indicator.
Observations: Acids turn blue litmus red, phenolphthalein stays colourless, methyl orange turns red/pink. Bases turn red litmus blue, phenolphthalein turns pink, methyl orange turns yellow.
Conclusion: Indicators change colour depending on whether the substance is acidic or basic.
▶ Activity 2.2 — Olfactory Indicators (Onion, Vanilla, Clove)
Materials: Onion-soaked cloth strips, vanilla essence, clove oil, dilute HCl, dilute NaOH.
Procedure: Add HCl and NaOH to onion strips, vanilla and clove oil separately. Note odour changes.
Observations: Onion — loses smell in NaOH (base), retains in HCl. Vanilla — loses smell in base. Clove oil — loses smell in acid (NaOH doesn’t affect it).
Conclusion: Onion and vanilla are olfactory indicators (respond to bases). Clove responds to acids. These can be used to detect acids/bases where colour indicators are not visible.
▶ Activity 2.3 — Acid + Metal → Hydrogen Gas
Materials: Dilute H₂SO₄, zinc granules, soap solution, burning candle. [CAUTION: Teacher’s assistance needed.]
Procedure: Add dilute H₂SO₄ to Zn granules. Pass evolved gas through soap solution. Bring a burning candle near H₂-filled bubble.
Observations: Bubbles on Zn surface. Soap bubbles filled with gas rise. The bubble burns with a ‘pop’ sound.
Conclusion: H₂ gas is evolved. Equation: Zn + H₂SO₄ → ZnSO₄ + H₂↑ [Displacement reaction]. All common acids (HCl, HNO₃, CH₃COOH) give similar results.
▶ Activity 2.4 — Base + Metal → Hydrogen Gas
Materials: Granulated zinc, NaOH solution.
Procedure: Add NaOH solution to zinc metal, warm gently. Test evolved gas by burning.
Observations: H₂ gas is evolved (pops near flame), just like with acids.
Conclusion: Bases can also react with certain metals (Zn, Al) to evolve H₂. Equation: 2NaOH(aq) + Zn(s) → Na₂ZnO₂(s) + H₂(g) [sodium zincate formed]. Not all metals react this way.
▶ Activity 2.5 — Acid + Carbonate/Bicarbonate → CO₂
Materials: Na₂CO₃ (test tube A), NaHCO₃ (test tube B), dilute HCl, lime water (Ca(OH)₂ solution).
Procedure: Add HCl to each test tube. Pass evolved gas through lime water.
Observations: Brisk effervescence (CO₂) in both tubes. Lime water turns milky white (CaCO₃ precipitate). On passing excess CO₂, milkiness disappears (Ca(HCO₃)₂ forms — soluble).
Equations: Na₂CO₃ + 2HCl → 2NaCl + H₂O + CO₂; NaHCO₃ + HCl → NaCl + H₂O + CO₂; Ca(OH)₂ + CO₂ → CaCO₃↓ + H₂O
▶ Activity 2.6 — Neutralisation (Acid + Base)
Materials: NaOH solution, HCl solution, phenolphthalein indicator.
Procedure: Add phenolphthalein to NaOH (turns pink). Add HCl drop by drop. Observe colour change. Then add NaOH back.
Observations: NaOH + phenolphthalein = pink. Adding HCl makes it colourless (acid neutralises base). Adding NaOH again restores pink colour.
Conclusion: Acid and base neutralise each other. NaOH + HCl → NaCl + H₂O. At endpoint (neutral), phenolphthalein is colourless.
▶ Activity 2.7 — Metal Oxide + Acid
Materials: Copper oxide (CuO, black powder), dilute HCl, beaker.
Procedure: Add dilute HCl slowly to CuO while stirring.
Observations: Black CuO dissolves. Solution turns blue-green (copper chloride CuCl₂ formed).
Conclusion: Metallic oxides are basic oxides — they react with acids to form salt + water, just like bases. CuO + 2HCl → CuCl₂ + H₂O. Non-metallic oxides (CO₂) react with bases and are acidic oxides.
▶ Activity 2.8 — Electrical Conductivity: Acids vs Glucose/Alcohol
Materials: HCl solution, H₂SO₄ solution, glucose solution, alcohol solution, 6V battery, bulb, two nails in cork.
Procedure: Pour each solution into beaker. Connect nails to battery through bulb. Observe whether bulb glows.
Observations: Bulb glows with HCl and H₂SO₄. Bulb does NOT glow with glucose and alcohol.
Conclusion: Acids produce ions (H⁺ and anions) in water which conduct electricity. Glucose/alcohol do not produce ions — hence not acidic despite containing hydrogen.
▶ Activity 2.9 — Dry HCl vs Wet HCl: Need for Water
Materials: Solid NaCl, concentrated H₂SO₄, dry and wet blue litmus paper.
Procedure: Add conc. H₂SO₄ to NaCl. Pass gas through dry litmus, then wet litmus.
Observations: Dry HCl gas does NOT change dry litmus. Moist/wet litmus paper turns red.
Conclusion: HCl gas is not acidic in the absence of water. H⁺ ions form ONLY in the presence of water: HCl + H₂O → H₃O⁺ + Cl⁻. Water is essential for ionisation and acidic behaviour.
▶ Activity 2.10 — Dilution of Acids/Bases: Exothermic Process
Materials: Water (10 mL), concentrated H₂SO₄, NaOH pellets, beaker.
Procedure: Add a few drops of conc. H₂SO₄ to water (NOT the other way). Touch base of beaker. Repeat with NaOH pellets.
Observations: The beaker becomes very hot — dissolving is highly exothermic for both acid and base.
Safety conclusion: Always add ACID to WATER. If water is added to acid, heat generated can cause the mixture to splash, causing burns. Dilution decreases H₃O⁺/OH⁻ concentration per unit volume.
▶ Activity 2.11 — Measuring pH of Common Solutions
Materials: Various solutions (saliva, lemon juice, cola, carrot juice, coffee, tomato juice, tap water, NaOH, HCl), universal indicator paper.
Procedure: Test pH of each solution using universal indicator paper.
Expected results: Gastric juice ~1.2, lemon ~2–3, cola ~3, coffee ~5, pure water ~7, sea water ~8, milk of magnesia ~10, NaOH ~14.
Conclusion: pH paper gives approximate pH values. Neutral = 7, acidic <7, basic >7.
▶ Activity 2.12 — Soil pH Test
Materials: Soil samples from various locations, water, test tube, universal indicator paper.
Procedure: Add 5 mL water to 2g soil, shake, filter, test filtrate pH with universal indicator paper.
Conclusion: Different soils have different pH values. Plants need specific pH for healthy growth. Acidic soil can be treated with quick lime, slaked lime or chalk (all alkaline) to neutralise the acidity.
▶ Activity 2.13 — Family of Salts
Task: Write formulae of: K₂SO₄, Na₂SO₄, CaSO₄, MgSO₄, CuSO₄, NaCl, NaNO₃, Na₂CO₃, NH₄Cl. Identify families.
Sulphate family: K₂SO₄, Na₂SO₄, CaSO₄, MgSO₄, CuSO₄ (share SO₄²⁻).
Sodium family: Na₂SO₄, NaCl, NaNO₃, Na₂CO₃ (share Na⁺).
Chloride family: NaCl, NH₄Cl (share Cl⁻).
Conclusion: Salts with the same positive or negative radical belong to the same family.
▶ Activity 2.14 — pH of Salt Solutions
Materials: Various salts, distilled water, litmus, pH paper.
Test: Dissolve NaCl, KNO₃, AlCl₃, ZnSO₄, CuSO₄, CH₃COONa, Na₂CO₃, NaHCO₃ in distilled water. Test with litmus and pH paper.
Results: NaCl, KNO₃ = neutral (pH 7). AlCl₃, ZnSO₄, CuSO₄ = acidic (pH <7, strong acid + weak base). Na₂CO₃, NaHCO₃, CH₃COONa = basic (pH >7, weak acid + strong base).
Conclusion: The pH of a salt solution depends on the relative strengths of the acid and base from which it was formed.
▶ Activity 2.15 — Water of Crystallisation (CuSO₄)
Materials: CuSO₄·5H₂O crystals, dry boiling tube, burner, water dropper.
Procedure: Heat crystals. Observe colour change and water droplets in tube. Add 2–3 drops of water to cooled anhydrous CuSO₄.
Observations: Blue crystals turn white on heating. Water droplets condense on cool upper tube. Adding water to white powder restores blue colour.
Conclusion: CuSO₄·5H₂O contains 5 water molecules of crystallisation. Heating removes them (anhydrous CuSO₄ = white). Adding water hydrates it back. This confirms water of crystallisation.

  ✏ Worked Examples
EXAMPLE 1

Write the balanced equation for dilute H₂SO₄ reacting with zinc granules. Identify the type of reaction.

Show Solution ▶
Word equation: Zinc + Sulphuric acid → Zinc sulphate + Hydrogen
Balanced: Zn(s) + H₂SO₄(aq) → ZnSO₄(aq) + H₂(g)
Check: Zn=1=1✓, H=2=2✓, S=1=1✓, O=4=4✓
Type: Displacement reaction (Zn displaces H from acid). Also produces H₂ gas — test: burns with pop sound.
EXAMPLE 2

Why does the colour of phenolphthalein change from pink to colourless when HCl is added to NaOH solution?

Show Solution ▶
NaOH is basic (produces OH⁻ ions) → phenolphthalein turns PINK in basic medium. When HCl is added, the acid and base neutralise each other: NaOH + HCl → NaCl + H₂O. The OH⁻ ions are consumed. The solution becomes neutral (or acidic if excess HCl). Phenolphthalein is colourless in neutral and acidic solutions → colour disappears. Adding NaOH again restores basicity → pink reappears.
EXAMPLE 3

Why do HCl and H₂SO₄ show acidic properties in water but dry HCl gas does not?

Show Solution ▶
Acidic behaviour is caused by H⁺(aq) ions. H⁺ ions cannot exist alone — they require water molecules to form H₃O⁺ (hydronium ions): HCl + H₂O → H₃O⁺ + Cl⁻. In dry HCl gas, there is no water present. So no ionisation occurs, no H⁺ ions are produced, and dry litmus paper does not change colour. Only in the presence of water does HCl dissociate and show acidic behaviour.
EXAMPLE 4

Five solutions have pH values 4, 1, 11, 7, 9. Identify each. Arrange in increasing order of H⁺ concentration.

Show Solution ▶
pH 1 = strongly acidic | pH 4 = weakly acidic | pH 7 = neutral | pH 9 = weakly alkaline | pH 11 = strongly alkaline.
Increasing H⁺ concentration means decreasing pH, so order: pH 11 → pH 9 → pH 7 → pH 4 → pH 1 (i.e., least H⁺ at pH 11, most H⁺ at pH 1).
EXAMPLE 5

Explain the chlor-alkali process. Why is it called ‘chlor-alkali’?

Show Solution ▶
When electricity is passed through aqueous NaCl (brine): 2NaCl(aq) + 2H₂O(l) → 2NaOH(aq) + Cl₂(g) + H₂(g)
It is called chlor-alkali because: “Chlor” refers to chlorine gas produced at the anode. “Alkali” refers to sodium hydroxide (an alkali) produced near the cathode. Three useful products: Cl₂ (water treatment, PVC), H₂ (fuel, fertilisers), NaOH (soaps, detergents, paper).
EXAMPLE 6

Metal compound A reacts with dilute HCl to produce effervescence. Gas extinguishes a burning candle. One product is CaCl₂. Write the balanced equation.

Show Solution ▶
Gas extinguishes a burning candle → it is CO₂ (not H₂, which burns). CO₂ is produced by acid + carbonate/bicarbonate. Product is CaCl₂ → Ca is involved. Compound A = CaCO₃ (calcium carbonate).
Balanced equation: CaCO₃(s) + 2HCl(aq) → CaCl₂(aq) + H₂O(l) + CO₂(g)
Ca=1=1✓, C=1=1✓, O=3=3✓, H=2=2✓, Cl=2=2✓
EXAMPLE 7

Why should curd and sour substances not be kept in brass or copper vessels?

Show Solution ▶
Curd and sour substances contain acids (lactic acid, citric acid). Acids react with metals (brass contains copper and zinc; copper vessels are copper). The reaction produces metal salts which contaminate the food and may be harmful. Also, the metal is corroded, ruining the vessel. This is why acidic foods should be stored in glass, ceramic or food-grade stainless steel containers.
EXAMPLE 8

Fresh milk has pH 6. What happens to pH as it turns to curd? Why?

Show Solution ▶
As milk turns to curd, bacteria convert lactose (milk sugar) into lactic acid. As lactic acid is produced, the concentration of H⁺ ions increases. pH decreases (becomes more acidic, pH drops below 6). This explains the sour taste of curd. The lower pH also helps preserve the curd temporarily by inhibiting harmful bacterial growth.
EXAMPLE 9

A milkman adds a small amount of baking soda to fresh milk. (a) Why does he shift the pH to slightly alkaline? (b) Why does this milk take longer to set as curd?

Show Solution ▶
(a) Baking soda (NaHCO₃) is a mild base. Making milk slightly alkaline (pH slightly above 7) provides a buffer against souring. When milk starts turning sour (lactic acid forms), the base first neutralises the acid before pH drops. This delays souring and extends shelf life.
(b) For milk to set as curd (coagulate), the pH must fall sufficiently (bacteria need acidic environment to grow and produce enough lactic acid). Since baking soda keeps neutralising the acid produced, it takes longer for the pH to fall to the level needed for curd formation.
EXAMPLE 10

Why is Plaster of Paris stored in moisture-proof containers?

Show Solution ▶
Plaster of Paris (CaSO₄·½H₂O) reacts with water to form gypsum (CaSO₄·2H₂O), a hard crystalline solid:
CaSO₄·½H₂O + 1½H₂O → CaSO₄·2H₂O (sets hard)
If exposed to moisture in the air, it will absorb water and set into hard gypsum even before use — making it completely useless. Moisture-proof storage keeps it dry and ready to use.
EXAMPLE 11

Equal lengths of Mg ribbon in HCl (tube A) and CH₃COOH (tube B) — same concentration. Which tube fizzes more vigorously and why?

Show Solution ▶
Test tube A (HCl) fizzes more vigorously. HCl is a strong acid — it completely ionises in water to produce a large concentration of H⁺ ions. CH₃COOH is a weak acid — it only partially ionises, producing fewer H⁺ ions at the same concentration. Since the reaction rate depends on H⁺ ion concentration, HCl reacts faster and produces H₂ gas more vigorously.
Reactions: Mg + 2HCl → MgCl₂ + H₂↑  |  Mg + 2CH₃COOH → (CH₃COO)₂Mg + H₂↑
EXAMPLE 12

10 mL NaOH is completely neutralised by 8 mL HCl. If 20 mL of same NaOH is taken, how much HCl is needed?

Show Solution ▶
10 mL NaOH requires 8 mL HCl.
Ratio: NaOH : HCl = 10 : 8 = 5 : 4
For 20 mL NaOH: HCl required = (8/10) × 20 = 16 mL
Answer: (d) 16 mL. Since the NaOH solution amount doubled (10→20 mL), the HCl required also doubles (8→16 mL).
EXAMPLE 13

Write balanced equations for: (a) dil. H₂SO₄ + Al; (b) dil. HCl + Fe filings; (c) NaHCO₃ heated.

Show Solution ▶
(a) 3H₂SO₄(dil) + 2Al(s) → Al₂(SO₄)₃(aq) + 3H₂(g) — Al=2=2✓, S=3=3✓, H=6=6✓
(b) 2HCl(aq) + Fe(s) → FeCl₂(aq) + H₂(g) — Fe=1=1✓, H=2=2✓, Cl=2=2✓
(c) 2NaHCO₃(s) →Heat Na₂CO₃(s) + H₂O(l) + CO₂(g) — Na=2=2✓, H=2=2✓, C=2=2✓, O=6=6✓

  📝 Practice Set A — Multiple Choice Questions (8 Questions)
Q1. A solution turns red litmus blue. Its pH is likely to be:
(a) 1   (b) 4   (c) 5   (d) 10

Show Answer ▶
(d) 10 — A substance that turns red litmus blue is basic (alkaline). Basic solutions have pH greater than 7. Among the options, only pH 10 > 7.
Q2. A solution reacts with crushed egg shells to give a gas that turns lime-water milky. The solution contains:
(a) NaCl   (b) HCl   (c) LiCl   (d) KCl

Show Answer ▶
(b) HCl — Egg shells are CaCO₃. An acid reacts with a carbonate to produce CO₂, which turns lime water milky. Of the options, only HCl is an acid. NaCl, LiCl, KCl are salts and won’t react with CaCO₃.
Q3. Which medicine is used for treating indigestion (excess stomach acid)?
(a) Antibiotic   (b) Analgesic   (c) Antacid   (d) Antiseptic

Show Answer ▶
(c) Antacid — Antacids (like Milk of Magnesia/Mg(OH)₂) are mild bases that neutralise excess HCl in the stomach: Mg(OH)₂ + 2HCl → MgCl₂ + 2H₂O. Antibiotics kill bacteria; analgesics relieve pain; antiseptics kill germs on surfaces.
Q4. Water of crystallisation in copper sulphate (CuSO₄·5H₂O) is:
(a) 1 molecule   (b) 2 molecules   (c) 5 molecules   (d) 10 molecules

Show Answer ▶
(c) 5 molecules — The formula CuSO₄·5H₂O indicates 5 water molecules per formula unit. These are the water of crystallisation. When heated, these 5 molecules are lost and white anhydrous CuSO₄ remains.
Q5. pH of acid rain is:
(a) exactly 7   (b) above 7   (c) less than 5.6   (d) between 6 and 7

Show Answer ▶
(c) Less than 5.6 — Normal rain water has pH ~5.6 (slightly acidic due to dissolved CO₂ forming carbonic acid). When SO₂ and NO₂ from burning fossil fuels dissolve in rain, pH falls below 5.6 — this is acid rain.
Q6. Bleaching powder is produced by the action of chlorine on:
(a) Dry NaCl   (b) Dry NaOH   (c) Dry slaked lime Ca(OH)₂   (d) Quick lime CaO

Show Answer ▶
(c) Dry slaked lime Ca(OH)₂ — Reaction: 2Ca(OH)₂ + 2Cl₂ → Ca(ClO)₂ + CaCl₂ + 2H₂O. The key word is “dry” slaked lime — if Ca(OH)₂ is wet, the product differs. Bleaching powder formula: Ca(ClO)₂.
Q7. Why does distilled water not conduct electricity but rain water does?
(a) Rain water is basic   (b) Rain water contains dissolved ions from gases   (c) Rain water is a mixture   (d) Distilled water is denser

Show Answer ▶
(b) Rain water contains dissolved ions from gases — CO₂ dissolves in rain to form H₂CO₃, which ionises: H₂CO₃ → H⁺ + HCO₃⁻. These ions carry electrical current. Distilled water is pure H₂O with no ions, so it cannot conduct electricity.
Q8. The common name of Ca(ClO)₂ is:
(a) Baking soda   (b) Washing soda   (c) Bleaching powder   (d) Plaster of Paris

Show Answer ▶
(c) Bleaching powder — Ca(ClO)₂ is calcium hypochlorite / bleaching powder. Baking soda = NaHCO₃. Washing soda = Na₂CO₃·10H₂O. Plaster of Paris = CaSO₄·½H₂O.

  📝 Practice Set B — Short Answer Questions (6 Questions)
Q1. What is a neutralisation reaction? Give two examples with equations.

Show Answer ▶
A neutralisation reaction is the reaction between an acid and a base to form a salt and water. The acid and base neutralise each other’s effect: Acid + Base → Salt + Water.
Example 1: NaOH(aq) + HCl(aq) → NaCl(aq) + H₂O(l)
Example 2: Ca(OH)₂(aq) + H₂SO₄(aq) → CaSO₄(aq) + 2H₂O(l)
Q2. What is water of crystallisation? How does heating affect copper sulphate crystals?

Show Answer ▶
Water of crystallisation is the fixed number of water molecules that are chemically combined with one formula unit of a crystalline salt. CuSO₄·5H₂O has 5 water molecules of crystallisation. On heating, these molecules are driven off: CuSO₄·5H₂O →Heat CuSO₄ + 5H₂O. Blue crystals turn white (anhydrous CuSO₄). Adding water again: white powder turns blue — water of crystallisation is restored.
Q3. Give two important uses each of baking soda and washing soda.

Show Answer ▶
Baking soda (NaHCO₃): (1) Making baking powder — CO₂ released makes bread/cake spongy. (2) Antacid — neutralises excess stomach acid; also used in soda-acid fire extinguishers.
Washing soda (Na₂CO₃·10H₂O): (1) Used in glass, soap, paper industries. (2) Removes permanent hardness of water; used as a cleaning agent at home.
Q4. Why do solutions of bases in water conduct electricity?

Show Answer ▶
When a base dissolves in water, it ionises to produce hydroxide ions (OH⁻) and metal cations: NaOH → Na⁺ + OH⁻. These ions (charged particles) move freely in the solution and carry electric current, enabling electrical conduction. Pure water (with no ions) does not conduct electricity. The more the base ionises, the better it conducts electricity (strong bases conduct better than weak bases).
Q5. What are olfactory indicators? Name two olfactory indicators and describe how they work.

Show Answer ▶
Olfactory indicators are substances whose smell (odour) changes when they come into contact with acidic or basic solutions — they detect acid/base through change in smell rather than colour change.
Onion: Strong onion smell is present in acid but disappears in base (NaOH destroys the odour-producing compounds). Vanilla: Pleasant vanilla smell disappears in basic solution. Both onion and vanilla are used as olfactory indicators when colour changes cannot be observed (e.g., in coloured solutions or for visually impaired students).
Q6. How is the pH of the mouth related to tooth decay? How can it be prevented?

Show Answer ▶
Bacteria in the mouth break down sugars and food particles left after eating to produce acids. When the pH of the mouth drops below 5.5, the acid corrodes the tooth enamel (calcium hydroxyapatite). This is the beginning of tooth decay (dental caries).
Prevention: (1) Clean mouth/brush teeth after meals to remove food particles and acids. (2) Use basic toothpaste — the base neutralises the acids formed by bacteria: Acid + Base → Salt + Water. This raises pH above 5.5, preventing enamel corrosion.

  📝 Practice Set C — Long Answer Questions (4 Questions)
Q1. What is the pH scale? Explain the importance of pH in four aspects of everyday life.

Show Answer ▶
The pH scale (0–14) measures hydrogen ion (H⁺) concentration. pH 7 = neutral; <7 = acidic; >7 = basic. Higher H⁺ → lower pH. A universal indicator shows different colours at different pH values.

1. Human Body: Body functions best at pH 7.0–7.8. Blood pH is ~7.4. Even slight changes can be fatal. Living organisms survive only within a narrow pH range.
2. Digestion: Stomach produces HCl (pH ~1.2) to digest food. Excess acid causes indigestion. Antacids (mild bases) neutralise excess acid and provide relief.
3. Tooth Decay: Bacteria produce acid from sugar. When mouth pH < 5.5, tooth enamel corrodes. Basic toothpaste neutralises acid and prevents decay.
4. Agriculture: Plants need specific pH for growth. Acidic soil (due to acid rain or chemical fertilisers) is treated with lime (CaO or Ca(OH)₂) to raise pH.

Q2. Describe all the chemical reactions of acids (with metals, carbonates, bases, metallic oxides). Give one example equation for each.

Show Answer ▶
1. Acid + Metal → Salt + H₂: Acids displace hydrogen from metals. Zn + H₂SO₄ → ZnSO₄ + H₂↑ [H₂ burns with pop]

2. Acid + Metal Carbonate → Salt + CO₂ + H₂O: Na₂CO₃ + 2HCl → 2NaCl + H₂O + CO₂↑ [CO₂ turns lime water milky]

3. Acid + Metal Hydrogencarbonate → Salt + CO₂ + H₂O: NaHCO₃ + HCl → NaCl + H₂O + CO₂↑

4. Acid + Base (Neutralisation) → Salt + H₂O: NaOH + HCl → NaCl + H₂O [pH 7 at endpoint]

5. Acid + Metal Oxide → Salt + H₂O: CuO + 2HCl → CuCl₂ + H₂O [black CuO → blue-green CuCl₂ solution]. Metallic oxides are basic oxides.

Q3. Explain the preparation, chemical formula, and uses of: (a) Bleaching powder; (b) Baking soda; (c) Washing soda.

Show Answer ▶
(a) Bleaching Powder Ca(ClO)₂: Cl₂ gas acts on dry slaked lime: 2Ca(OH)₂ + 2Cl₂ → Ca(ClO)₂ + CaCl₂ + 2H₂O. Uses: bleaching cotton/linen/paper/washed clothes; oxidising agent in industries; disinfecting drinking water.

(b) Baking Soda NaHCO₃: NaCl + H₂O + CO₂ + NH₃ → NH₄Cl + NaHCO₃. Mild non-corrosive basic salt. Uses: baking powder (CO₂ makes bread spongy: 2NaHCO₃ →Heat Na₂CO₃ + H₂O + CO₂); antacid (neutralises excess stomach acid); soda-acid fire extinguisher.

(c) Washing Soda Na₂CO₃·10H₂O: Heat NaHCO₃ → Na₂CO₃; add water: Na₂CO₃ + 10H₂O → Na₂CO₃·10H₂O. Uses: glass, soap, paper industries; manufacture of sodium compounds like borax; domestic cleaning agent; removes permanent hardness of water.

Q4. What are strong and weak acids? How does the activity of an acid depend on ionisation? Compare HCl and CH₃COOH at the same concentration.

Show Answer ▶
Strong acids completely ionise in water to produce a large number of H⁺ ions: HCl → H⁺ + Cl⁻ (complete). Strong acids: HCl, H₂SO₄, HNO₃.
Weak acids partially ionise: CH₃COOH ⇌ CH₃COO⁻ + H⁺ (partial). Weak acids: CH₃COOH, H₂CO₃, H₃PO₄.

Comparison: At the same molar concentration (e.g., 1M): 1M HCl has many more H⁺ ions than 1M CH₃COOH. HCl has a lower pH and reacts more vigorously with metals (Mg ribbon fizzes more in HCl). HCl conducts electricity better (more ions). The activity and reactivity of an acid directly depends on the concentration of H⁺ ions in solution — more H⁺ = more reactive/stronger acid.

  📝 Practice Set D — Numerical / Equation Problems (4 Questions)
Q1. Write balanced equations for: (a) dil. HCl + Mg ribbon; (b) dil. H₂SO₄ + aluminium powder.

Show Answer ▶
(a) Mg(s) + 2HCl(aq) → MgCl₂(aq) + H₂(g) — Mg=1=1✓, H=2=2✓, Cl=2=2✓. Displacement reaction; H₂ burns with pop.
(b) 2Al(s) + 3H₂SO₄(aq) → Al₂(SO₄)₃(aq) + 3H₂(g) — Al=2=2✓, H=6=6✓, S=3=3✓, O=12=12✓. Displacement reaction; H₂ evolved.
Q2. Write the equation for heating baking soda. What gas is produced? How would you test for it?

Show Answer ▶
2NaHCO₃(s) →Heat Na₂CO₃(s) + H₂O(l) + CO₂(g)
Na=2=2✓, H=2=2✓, C=2=2✓, O=6=6✓
Gas produced: CO₂ (carbon dioxide).
Test: Pass the gas through calcium hydroxide (lime water) — Ca(OH)₂(aq) + CO₂(g) → CaCO₃(s)↓ + H₂O(l). Lime water turns milky white → confirms CO₂. On passing excess CO₂, white precipitate dissolves again (Ca(HCO₃)₂ forms).
Q3. Write the reaction between Plaster of Paris and water. Why is it called Plaster of ‘Paris’?

Show Answer ▶
CaSO₄·½H₂O + 1½H₂O → CaSO₄·2H₂O (Gypsum)
Plaster of Paris (white powder) absorbs water and sets into hard gypsum. This setting is irreversible — that is why it must be stored in moisture-proof containers.
It is called “Plaster of Paris” because large deposits of gypsum are found near Paris, France. The plaster was historically made there from local gypsum deposits, giving it the name.
Q4. Solution A has pH 6, Solution B has pH 8. (a) Which has more H⁺? (b) Which is acidic/basic? (c) If B is diluted, what happens to its pH?

Show Answer ▶
(a) Solution A (pH 6) has more H⁺ ions — Lower pH means higher H⁺ concentration. pH and H⁺ are inversely related.
(b) Solution A (pH 6) is acidic (pH <7) — could be urine or milk. Solution B (pH 8) is basic/alkaline (pH >7) — could be sea water or egg white.
(c) If Solution B (basic) is diluted, water is added, which decreases OH⁻ concentration per unit volume. pH decreases (moves towards 7, neutral). Dilution of a basic solution moves its pH towards 7.

  💡 Important Facts to Remember
⚡ Acid + Metal Carbonate vs Acid + Metal: The gas produced is different — carbonates give CO₂ (extinguishes candle, turns lime water milky), metals give H₂ (burns with pop). Don’t confuse these tests!
⚡ Litmus — Origin: Litmus is extracted from Thallophyta (lichen). When neutral: purple. In acid: red. In base: blue. Turmeric is another natural indicator (yellow in acid/neutral → reddish-brown in base).
⚡ Lime Water Test: Ca(OH)₂ + CO₂ → CaCO₃↓ + H₂O (turns milky). Excess CO₂: CaCO₃ + H₂O + CO₂ → Ca(HCO₃)₂ (milkiness disappears — soluble bicarbonate).
⚡ Baking Powder vs Baking Soda: Baking soda = NaHCO₃ alone. Baking powder = NaHCO₃ + a mild edible acid (tartaric acid). When heated or wetted: NaHCO₃ + H⁺ → CO₂ + H₂O + salt. CO₂ makes baked goods light and spongy.

  📚 Chapter Summary

Chapter 2 — Acids, Bases and Salts: Key Points

Acids
Sour taste • Turn blue litmus red • pH <7 • Produce H⁺(aq)/H₃O⁺ in water • React with metals → H₂ • React with carbonates → CO₂ • React with bases → salt + water
Bases/Alkalis
Bitter taste • Soapy feel • Turn red litmus blue • pH >7 • Produce OH⁻(aq) in water • React with metals (Zn, Al) → H₂ • Alkalis = water-soluble bases
pH Scale
0–14 range • pH 7 = neutral • pH <7 = acidic • pH >7 = alkaline • Universal indicator shows colours • H⁺ ↑ = pH ↓
Salts
Strong acid + Strong base → neutral salt (pH 7) • Strong acid + Weak base → acidic salt • Weak acid + Strong base → basic salt
Important Chemical Formula Made From Key Use
Bleaching powder Ca(ClO)₂ Cl₂ + Ca(OH)₂ Bleaching, disinfection
Baking soda NaHCO₃ NaCl + CO₂ + NH₃ Baking, antacid, fire extinguisher
Washing soda Na₂CO₃·10H₂O Heat NaHCO₃ + recrystallise Glass, soap, paper; hard water
Plaster of Paris CaSO₄·½H₂O Heat gypsum at 373K Fractured bones, toys, decor
Sodium hydroxide NaOH Chlor-alkali process (electrolysis of brine) Soaps, detergents, paper

  🏆 8-Point Exam Quick-Check
✅ Must-Know Facts

1. All acids produce H⁺(aq) in water; all bases produce OH⁻(aq). Water is essential for ionisation.

2. Neutralisation: H⁺(aq) + OH⁻(aq) → H₂O(l). Salt and water formed.

3. Chlor-alkali process gives three products: Cl₂ (anode), H₂ (cathode), NaOH (near cathode).

4. Tooth decay starts at pH < 5.5. Acid rain pH < 5.6. Body works at pH 7.0–7.8.

5. CO₂ test = lime water turns milky. H₂ test = burns with pop sound.

⚠ Common Exam Traps

Trap 1: All alkalis are bases but NOT all bases are alkalis (only water-soluble ones).

Trap 2: Dry HCl does NOT show acidic behaviour — water is essential for ionisation.

Trap 3: Always add acid TO water (A to W), never water to acid — risk of splash/burns.

Trap 4: Glucose and alcohol contain H but are NOT acids — they don’t produce H⁺ in water.

Trap 5: Higher pH does NOT mean more H⁺ — it means LESS H⁺ (inverse relationship).

This comprehensive study page for Class 10 Science Chapter 2 — Acids, Bases and Salts covers all CBSE and NCERT topics including properties of acids and bases, indicators, olfactory indicators, the pH scale, neutralisation reactions, the chlor-alkali process, bleaching powder, baking soda, washing soda, water of crystallisation, gypsum and Plaster of Paris. Includes 13 fully solved worked examples, 4 practice sets with answers, all 15 lab activities as interactive accordions, and HTML table diagrams of key experiments. Perfect for CBSE Class 10 board exam revision. Visit School Revise for more Grade 10 NCERT Science study materials.

© 2025 School Revise — All Rights Reserved — CBSE / NCERT Science Class 10 — Chapter 2: Acids, Bases and Salts. Curriculum reference: NCERT Science Textbook, Class 10, Chapter 2. All content original and independently written by School Revise.

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